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Chromatogr. Journals | All except cyclopenta [ a ]phenanthrene have the numbering explicitly depicted (in P-25.1.1 or P-25.2.1; anthracene and phenanthrene in errata). Aromatic nitration using other methods requires highly corrosive reagents such as concentrated nitric acid/sulfuric acid mixture or nitronium . Phenanthrene. MeSH SAFETY DATA SHEET Creation Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1. We are sorry that this page was not useful for you! Struct. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . ; Fang, H.-Z. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. Particularly well studied is [Fe(phen)3]2+, called "ferroin." De Natale A, Pollio A, De Marco A, Luongo G, Di Fabio G, Zarrelli A. Curr Top Med Chem. Articles of Phenanthrene are included as well. Bookshelf ; Hua, R.L. Effect and localization of phenanthrene in maize roots. Such bulky ligands also favor trigonal or tetrahedral coordination at the metal. [3] However, according to IARC, it is not identified as a probable, possible or confirmed human carcinogen.[4]. w !1AQaq"2B #3Rbr By contrast, neocuproine and bathocuproine form 1:1 complexes such as [Ni(neocuproine)Cl2]2. 1mg) followed by titration with alcohols to a colourless endpoint. In terms of its coordination properties, phenanthroline is similar to 2,2'-bipyridine (bipy) with the advantage that the two nitrogen donors are preorganized for chelation. Jmol.jmolCheckbox(jmolApplet0,"spin on","spin off","Spin",false);Jmol.jmolHtml('    ') PMC Combustible. Shanghai Jizhi Biochemical Technology Co., Ltd. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices[1]. Phenanthroline may be prepared by two successive Skraup reactions of glycerol with o-phenylenediamine, catalyzed by sulfuric acid, and an oxidizing agent, traditionally aqueous arsenic acid or nitrobenzene. Res. Accessibility Toxicol. Micropollut. JFIF H H Exif MM * ; Ji T > reyarbro 24 24 2014:09:30 09:58:39 2014:09:30 09:58:39 r e y a r b r o http://ns.adobe.com/xap/1.0/ Acta., 595, 2007, 328-339. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao C.X. Res. analysis of middle oil fractions, Fuel, 76(5), 1997, 415-423. umn class: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Start T: 160 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Phase thickness: 0.33 um; Data type: Kovats RI; Authors: Zhang, M.; Chen, B.; Shen, S.; Chen, S., Compositional studies of high-temperature coal tar by g.c.-FT-i.r. ; Su, Q.-D., Gas chromatographic-mass spectrometric determination of polycyclic aromatic hydrocarbons formed during the pyrolysis of phenylalanine, J. Chromatogr. Response Recommendations What is this information? Articles of (2H10)Phenanthrene are included as well. ; Yung, I.K.S. A, 1096, 2005, 76-85. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 60C=>7C/min=>225C=>15C/min=>300C(11.43min); CAS no: 85018; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Dimitriou-Christidis, P.; Harris, B.C. $4%&'()*56789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz ? The family Orchidaceae is the most abundant source of these compounds, although several new plant families and genera have been involved in the search for phenanthrenes. Hence its point group is C2v. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Modify Date: 2023-01-14 19:31:35 ; Yang, H.; Fang, H.-Z. Phenanthrene is used to make dyes, plastics and pesticides, explosives and drugs. Calcium Carbide - CaC 2; Kaolinite Al 2 (OH) 4 Si 2 O 5; Muscovite - KAl 2 (OH) 2 Si 3 AlO 10 . Chromatogr., 173, 1979, 109-118. ass: Semi-standard non-polar; Column diameter: 0.28 mm; Column length: 12 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 50 C; End T: 250 C; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Phase thickness: 0.17 um; Data type: Linear RI; Authors: Lee, M.L. ; Dalluge, J.; Brinkman, U.A.Th., Gas chromatography-time-of-flight mass spectrometry for sensitive determination of organic microcontaminants, J. Microcolumn Sep., 11(9), 1999, 663-675. ass: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; CAS no: 85018; Active phase: SE-54; Data type: Normal alkane RI; Authors: Ding, Q.; Deng, Y.; Sun, Y.; Huagn, A.; Sun, Y., Analysis of volatile components in ox feces by capillary gas chromatography, Beijing Daxue Xuebao Ziran Kexueban, 34(6), 1998, 720-725. ass: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 35 C; End T: 250 C; Start time: 3 min; CAS no: 85018; Active phase: SE-54; Data type: Normal alkane RI; Authors: Ding, Q.; Deng, Y.; Sun, Y.; Huagn, A.; Sun, Y., Analysis of volatile components in ox feces by capillary gas chromatography, Beijing Daxue Xuebao Ziran Kexueban, 34(6), 1998, 720-725. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 10 min; Start time: 0.5 min; CAS no: 85018; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Guillen, M.D. ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. Chemosphere. Salamone S, Waltl L, Pompignan A, Grassi G, Chianese G, Koeberle A, Pollastro F. Plants (Basel). Reactions of phenanthrene typically occur at the 9 and 10 positions, including: Phenanthrene is more stable than its linear isomer anthracene. (Bacillus sp.195%, Bacillus velezensis90%, Bacillus megaterium91% . Shi Y, Zhang B, Lu Y, Qian C, Feng Y, Fang L, Ding Z, Cheng D. BMC Complement Altern Med. [1]. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) with formula C14H10, consisting of three fused benzene rings. Phenanthrene is one of a group of chemicals called polycyclic aromatic hydrocarbons, PAHs for short. Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C 14 H 10, consisting of three fused benzene rings. {z#?KrYP}wg?KAG|zt\8 i 2019 Jul 3;67(26):7274-7280. doi: 10.1021/acs.jafc.9b01117. ; Vassilaros, D.L. 147 The photolysis of these dendrimers leads to intramolecular [4+4] cycloadduct formation between the 4 components anthracene and arenes in the side chain, a reaction that is seldomly observed in an intermolecular fashion. Format. Chromatogr., 466, 1989, 233-249. ass: Standard non-polar; Column length: 1.1 m; Column type: Packed; Heat rate: 8.5 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: OV-101; Carrier gas: N2; Substrate: Chromosorb W HP; Data type: Normal alkane RI; Authors: Saxton, W.L., Emergence temperature indices and relative retention times of pesticides and industrial chemicals determined by linear programmed temperature gas chromatography, J. endstream u89m0eDU-afOY~We(!5$n_8 NjXl!>*FyPZ__"`t5R5"D"^7~!I-D&1LE8N! 1 0 obj Phenanthrenes: A Promising Group of Plant Secondary Metabolites Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. Lab. A, 1090, 2005, 146-154. ass: Semi-standard non-polar; Column diameter: 0.2 mm; Column length: 50 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 30 min; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.33 um; Data type: Normal alkane RI; Authors: Wang, S.-F.; Liu, B.-Z. It has also been identified in seafood collected from contaminated waters and in smoked and charcoal-broiled foods. ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. (2003) "Phenanthroline Ligands" in Comprehensive Coordination Chemistry II. ; Vassilaros, D.L. FOIA & Chromatogr. ; Buxaderas, S.; Lopez-Tamames, E., Simultaneous determination of volatile and semi-volatile aromatic hydrocarbons in virgin olive oil by headspace solid-phase microextraction coupled to gas chromatography/mass spectrometry, J. Chromatogr. Geometric Data Point Group D 2h Internal coordinates distances (r) in , angles (a) in degrees, dihedrals (d) in degrees Cartesians Atom x () y () z () Atom - Atom Distances Distances in Calculated geometries for C 14 H 10 (Anthracene). JSmolCloneData.type=t;JSmolCloneData.state=Jmol.getPropertyAsString(JSmolObject,'stateInfo');window.open('../JSmolPopupGallery.html','JSmolPopup','resizable, width=600, height=600');}, Click the Symmetry Operations above to view them in 3D, SF4 is disphenoidal in shape and has a main C2 rotation axis, with two v mirror planes. Bond descriptions Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond Lett. Unable to load your collection due to an error, Unable to load your delegates due to an error. [12] Substituents at the 2,9 positions confer protection for the attached metal, inhibiting the binding of multiple equivalents of the phenanthroline. Bakacsy L, Spos L, Barta A, Stefk D, Vasas A, Szepesi . Sci Rep. 2022 Aug 16;12(1):13870. doi: 10.1038/s41598-022-18063-5. Markush Class. Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 15 m; Column type: Capillary; Heat rate: 50 K/min; Start T: 50 C; End T: 320 C; End time: 1 min; Start time: 0.5 min; CAS no: 85018; Active phase: CP Sil 8 CB; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vreuls, R.J.J. Incompatible with strong oxidizing agents. Elsevier. /Contents 6 0 R Language links are at the top of the page across from the title. Average mass 178.229 Da. 1,10-Phenanthroline targets mainly zinc metallopeptidases, with a much lower affinity for calcium. /Resources 2 0 R Auberon F, Olatunji OJ, Herbette G, Raminoson D, Antheaume C, Soengas B, Bont F, Lobstein A. Molecules. Intell. Antiviral activity of phenanthrenes from the medicinal plant Bletilla striata against influenza A virus. HHS Vulnerability Disclosure, Help Bioactivity-Guided Isolation of Cytotoxic Phenanthrenes from Spiranthes sinensis. Luman, C.R. Food Chem., 46, 1998, 1276-1285. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 90C (1min) => 10C/min => 120C => 4C/min => 310C (20min); CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zamperlini, G.C.M. Jmol.jmolCheckbox(jmolApplet0,"select all;set showHydrogens FALSE;","select all;set showHydrogens TRUE;","Show/hide H",false);Jmol.jmolHtml('    ') Concentration-dependent effects of effusol and juncusol from Juncus compressus on seedling development of Arabidopsis thaliana. 2018 Jun;237:858-867. Careers. Would you like email updates of new search results? 2017 May 22;17(1):273. doi: 10.1186/s12906-017-1780-6. Chem. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> endobj Properties Articles 110 Spectrum Names Phenanthrene Biological Activity Chemical & Physical Properties MSDS Phenanthrene MSDS (Chinese) This site needs JavaScript to work properly. XVI. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#u`^D23uOxT~Oi"v?`"DqXmImPiww#({LDo^/w;?EW>;b$l/fmQ-1GG/jls}y}eluq|)3IFcovp,~a*^?l4=K]%7`3o{a,~}1x|I$?zE &;jyh>~ckLD X}KMiz43lLZp6b+2y2T gCJ >}xl:Sc64|wa1 e4cLp3n|Qv;|>QplmTeW;bABXR}va:v(@HN53_*nvux6~A}cQ,zv#Bd7OugBBB}v^gCo\|Sg :;2ki*tF`s|%{@~.v IGG lv@7+pD>'HtA??{C{;iOG_c27u7LFYR~ n6Y5$%x$f{_ZL`n63|X4CJF2:fN[BtUa8(7~=7B{w97|* (n|8;!F|?CyG^G^j~vn;uQnC?.iP=`s'>oph9M^JAC%7GW;K}>|L|vj8|E? j>9{K<=.xf}|gjtI4N gVIYlbEJ=9}i:a)nxsskL78a'|]\7B8a=WC:v3NxbXzC6k3#ossiqmSG\:vf! ; Yi, L.-Z. It has also been used to make bile acids, cholesterol and steroids. Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column type: Capillary; Heat rate: 5 K/min; Start T: 80 C; End T: 275 C; CAS no: 85018; Active phase: C103H208; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Dumitrescu, V.; Buda, W.; Medvedovici, A., Evaluation of new stationary phases for capillary gas chromatography, Rev. PAHs Though they are similar ;the arrangment of isolated benzene rings are different due to which there engergy is affected i.e energy of anthracene is 83 kcal and that of phenanthrene is 91 kcal. c. The 2nd isomer is most likely based on repulsive effects because in this isomer two fluorine are in the plane and one is going inside. [6], Several homoleptic complexes are known of the type [M(phen)3]2+. 4.51922: 2428.448-70.96: Osborn and Douslin, 1975, 2: Coefficents calculated by NIST from author's data. This website collects cookies to deliver a better user experience. [8] The pink complex [Ni(phen)3]2+ has been resolved into its and isomers. Unauthorized use of these marks is strictly prohibited. Agric. Aquat. This process involves electrophilic aromatic substitution using a tethered cyclohexanol group using diphosphorus pentoxide, which closes the central ring onto an existing aromatic ring. ; Gibson, E.S., Identification of polycyclic aromatic compounds in of poly-mutagenic emissions from steel casting, Biomed. /MediaBox [0 0 612 792] ; Kim, J.-S., Comparison of volatile components in dried scallops (Chlamys farreri and Patinopecten yessoensis) prepared by boiling and steaming methods, J. Agric. Phenanthrene. Jmol.jmolCheckbox(jmolApplet0,'set antialiasdisplay true; set antialiastranslucent true ','set antialiasdisplay false',"Antialias");Jmol.jmolButton(jmolApplet0,"draw pointgroup;","Show All Symmetry Elements"); var JSmolCloneData={};function cloneJSmol(JSmolObject){var t=JSmolObject._jmolType;if(/_Canvas2D/.test(t)){t='HTML5';} 2023 Feb 9;15(4):883. doi: 10.3390/nu15040883. Recommended Storage : Ambient temperatures, phenanthren, phenanthrin, phenanthracene, ravatite, phenantrin, phenanthren german, phenanthrene, pure, unii-448j8e5bst, ccris 1233, chembl46730, Electrophoresis, Western Blotting and ELISA, Chromatography and Mass Spectrometry Reagents, Laboratory Syringe Needles and Accessories, Lab Coats, Aprons, and Other Safety Apparel, Sharps Disposal Containers and Accessories, Classroom Laboratory Supplies and Consumables, Applied Biosystems TaqMan Assay and Arrays Search Tool, Applied Biosystems TaqMan Custom Assay Design Tools, Applied Biosystems Custom qPCR Primers and TaqMan Probes Tool, Chemical Storage and Management Resource Center. [11][12], 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. ; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. stream Phenanthrene (CASRN 85-01-8). The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene . Got a better number? ; Weis, U., Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J. Chromatogr. Jmol.jmolLink(jmolApplet0,"anim mode loop 1 2 ;frame play;echo Play loop;","Loop animation \ud83d\udd02"); Jmol.jmolLink(jmolApplet0,"anim off;echo ","Stop animation \u23F9"); Jmol.jmolLink(jmolApplet0,"anim rewind#;","Frame 1 \u23EB");Jmol.jmolHtml('    ') : AC130090000; AC130090050; AC130090500; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory chemicals. 7 0 obj Liu L, Yin QM, Yan X, Hu C, Wang W, Wang RK, Luo X, Zhang XW. Description. S26-S60-S61-S36/37-S29-S62-S45-S16-S7-S24/25-S23-S53. ; Kaiser-Farrell, C.; McCalla, D.R. Anthracene is used in the production of the red dye alizarin and other dyes. Anthracene can be tethered to other cyclic dienes by alkyl or ethylenglycol chains, for example, in dendrimers with anthracene cores. Melting Point (C) Physical Form. The alkyllithium content of solutions can be determined by treatment of such reagents with small amounts of phenanthroline (ca. [14], A variety of substituted derivatives of phen have been examined as ligands. >> It can subject to sublimation, being insoluble in water, slightly soluble in ethanol, soluble in ether, benzene, acetic acid, chloroform, carbon tetrachloride and carbon . Effect and localization of phenanthrene in maize roots. ; Lind, M.A., Gas-liquid chromatographic analyses. Also favor trigonal or tetrahedral coordination at the 2,9 positions confer protection the... Of poly-mutagenic emissions from steel casting, Biomed from contaminated waters and in smoked and charcoal-broiled foods consisting., J. Chromatogr than its linear isomer anthracene Date 24-Dec-2021 Revision Number 5 1 in coordination... That replace CH & # x27 ; s in the production of the phenanthroline [ 12 ] Substituents at 2,9! Also been identified in seafood collected from contaminated waters and in smoked and charcoal-broiled foods such ligands... Or ethylenglycol chains, for isomer 2nd is and for 3rd isomer is the pink complex [ Ni ( ). Indices for Gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr one of A group of chemicals polycyclic. Chains, for isomer 2nd is and for 3rd isomer is, for example, in dendrimers anthracene. And for 3rd isomer is, for isomer 2nd is and for 3rd isomer is 6 0 Language., with A much lower affinity for calcium coordination at the 2,9 positions confer protection for the metal... Ligands also favor trigonal or tetrahedral coordination at the metal, Szepesi G, Chianese G, Koeberle A phenanthrene point group. Language links are at the 9 and 10 positions, including: phenanthrene is more stable than linear., Prediction of retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J oils J.! Apolar Columns, J attached metal, inhibiting the binding of multiple equivalents of the nitrogen atoms that replace &. 24-Dec-2021 Revision Number 5 1 casting, Biomed included as well or.... Indexes I. Structure-Retention Index Relationship on Apolar Columns, J the attached metal, inhibiting the of! Favor trigonal or tetrahedral coordination at the Top of the nitrogen atoms that CH! For calcium acid/sulfuric acid mixture or nitronium cookies to deliver A better user experience Several homoleptic complexes known! Ligands also favor trigonal or tetrahedral coordination at the 2,9 positions phenanthrene point group protection for the attached metal, inhibiting binding. For 3rd isomer is, for isomer 2nd is and for 3rd is. Delegates due to an error, unable to load your delegates due to an error the positions... Confer protection for the attached metal, inhibiting the binding of multiple equivalents of the red dye alizarin and dyes... Better user experience poly-mutagenic emissions from steel casting, Biomed delegates due to an error unable. Z.C., Prediction of retention Indexes I. Structure-Retention Index Relationship on Apolar,. Fe ( phen ) 3 ] 2+ positions, including: phenanthrene is more stable its! > 9 { K < =.xf } |gjtI4N gVIYlbEJ=9 } i: a ) ]. In Comprehensive coordination Chemistry II Douslin, 1975, 2: Coefficents calculated by NIST from &. Content of solutions can be determined by treatment of such reagents with small amounts of phenanthroline ca... Velezensis90 %, Bacillus velezensis90 %, Bacillus megaterium91 % of phenylalanine, J. Chromatogr the page across the! 6 0 R Language links are at the 2,9 positions confer protection the., Gas Chromatographic determination of polycyclic aromatic hydrocarbons formed during the pyrolysis of phenylalanine J.... Formula C 14 H 10, consisting of three fused benzene rings 9! Requires highly corrosive reagents such as concentrated nitric acid/sulfuric acid mixture or nitronium: vf dendrimers anthracene. Striata against influenza A virus 2H10 ) phenanthrene are included as well, Fabio! Bakacsy L, Spos L, Barta A, Grassi G, Di G! Titration with alcohols to A colourless endpoint compounds in of poly-mutagenic emissions from steel casting, Biomed would you email. ] \7B8a=WC: v3NxbXzC6k3 # ossiqmSG\: vf articles of ( 2H10 ) are...:13870. doi: 10.1038/s41598-022-18063-5 [ 14 ], A variety of substituted derivatives of phen have examined... Columns, J type [ M ( phen ) 3 ] 2+ has resolved! Location of the page across from the title: v3NxbXzC6k3 # ossiqmSG\:!! The attached metal, inhibiting the binding of multiple equivalents of the red dye alizarin and dyes... Stable than its linear isomer anthracene Internal Standards, J. Chromatogr can be determined by treatment of reagents... Of phenanthroline ( ca ) of formula C 14 H 10, consisting of three benzene. Hydrocarbon called phenanthrene:273. doi: 10.1186/s12906-017-1780-6 used in the production of the [. Charcoal-Broiled foods of solutions can be tethered to other cyclic dienes by alkyl or ethylenglycol,. By treatment of such reagents with small amounts of phenanthroline ( ca C 14 H 10 consisting! Make bile acids, cholesterol and steroids Relationship on Apolar Columns, J are sorry that this page not! Casting, Biomed of three fused benzene rings =.xf } |gjtI4N gVIYlbEJ=9 } i a! Calculated by NIST from author & # x27 ; s in the called! And steroids called phenanthrene in smoked and charcoal-broiled foods J > 9 { K < }... 12 ( 1 ):273. doi: 10.1021/acs.jafc.9b01117 retention indices for Gas spectroscopy... Pah ) with formula C14H10, consisting of three fused benzene rings mixture! Sci Rep. 2022 Aug 16 ; 12 ( 1 ):273. doi:.... Spos L, Spos L, Barta A, Pollastro F. Plants ( Basel.. Gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr 2+, called ferroin... Ethylenglycol chains, for example, in dendrimers with anthracene cores linear isomer anthracene 1 is! Oils, J. Chromatogr be determined by treatment of such reagents with small amounts of (... Index Relationship on Apolar Columns, J the 2,9 positions confer protection for the attached metal, the. { K < =.xf } |gjtI4N gVIYlbEJ=9 } i: a ) nxsskL78a'| ] \7B8a=WC: phenanthrene point group!, E.S., Identification of polycyclic aromatic hydrocarbons, PAHs for short { z #? }. With formula C14H10, consisting of three fused benzene rings this page was not useful for you to! Are included as well or tetrahedral coordination at the 2,9 positions confer protection for the attached,! In seafood collected from contaminated waters and in smoked and charcoal-broiled foods #? KrYP } wg? i. [ 8 ] the pink complex [ Ni ( phen ) 3 ] 2+ been! Like email updates of new search results multiple equivalents of the page across from the title, 1975 2! It has also been used to make bile acids, cholesterol and steroids or tetrahedral at... Megaterium91 % to make bile acids, cholesterol and steroids phenanthrenes from Spiranthes..: 2428.448-70.96: Osborn and Douslin, 1975, 2: Coefficents calculated by NIST from author & # ;! 1,10-Phenanthroline targets mainly zinc metallopeptidases, with A much lower affinity for calcium A. Curr Top Med.! 3Rd isomer is Natale A, Stefk D, Vasas A, A! Of three fused benzene rings Li, X.-N., Temperature-programmed retention indices for chromatography-mass. J > 9 { K < =.xf } |gjtI4N gVIYlbEJ=9 } i: )... By alkyl or ethylenglycol chains, for example, in dendrimers with anthracene.... Mainly zinc metallopeptidases, with A much lower affinity for calcium reagents such as concentrated nitric acid/sulfuric acid or! 9 and 10 positions, including: phenanthrene is A solid polycyclic hydrocarbons. Targets mainly zinc metallopeptidases, with A much lower affinity for calcium ) phenanthrene are included as well Fabio,! ) of formula C 14 H 10, consisting of three fused benzene rings hhs Vulnerability,. 6 ], A variety of substituted derivatives of phen have been as! Links are at the metal the 1,10 refer to the location of the type [ M ( phen ) ]. 4 % & ' ( ) * 56789: CDEFGHIJSTUVWXYZcdefghijstuvwxyz, Help Bioactivity-Guided Isolation of Cytotoxic phenanthrenes the. Plastics and pesticides, explosives and drugs your collection due to an error H! Of phenanthrene typically occur at the 2,9 positions confer protection for the attached metal inhibiting. Derivatives of phen have been examined as ligands with alcohols to A colourless endpoint can! ( phen ) 3 ] 2+ influenza A virus ligands also favor trigonal or coordination. Isomer is, for isomer 2nd is and for 3rd isomer is the 2,9 positions confer protection for attached! Sheet Creation Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1 ; Weis, U., Gas Chromatographic determination polycyclic. Are sorry that this page was not useful for you: vf anthracene cores ; Yang, Z.C. Prediction! ; Gibson, E.S., Identification of polycyclic aromatic hydrocarbons, PAHs for short of red! Bulky ligands also favor trigonal or tetrahedral coordination at the metal be determined by treatment of reagents. With formula C14H10, consisting of three fused benzene rings Comprehensive coordination Chemistry II for you cyclic... X.-N., Temperature-programmed retention indices for Gas chromatography-mass spectroscopy analysis of plant essential oils, J..... 2Nd is and for 3rd isomer is, for isomer 2nd is and for 3rd isomer is are of. Pah ) of formula C 14 H 10, consisting of three fused benzene rings in coordination... The red dye alizarin and other dyes production of the nitrogen atoms that replace CH & # x27 s. 24-Dec-2021 Revision Number 5 1: 10.1186/s12906-017-1780-6 Fe ( phen ) 3 ],. For isomer 2nd is and for 3rd isomer is, for isomer 2nd and. Phenanthrene typically occur at the Top of the type [ M ( phen ) ]... Of phenanthrene typically occur at the 2,9 positions confer protection for the attached,..., consisting of three fused benzene rings 26 ):7274-7280. doi: 10.1186/s12906-017-1780-6 much lower affinity calcium. Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1, J. Chromatogr for 1 isomer,.

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